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The Carnot cycle is a theoretical thermodynamic cycle proposed by Nicolas Léonard Sadi Carnot in 1824 and expanded upon by others in the 1830s and 1840s. It provides an upper limit on the efficiency that any classical thermodynamic cycle can achieve during the conversion of thermal energy into work, or conversely, the efficiency of a refrigeration system in creating a temperature difference (e.g. refrigeration) by the application of work to the system. It is not an actual thermodynamic cycle but is a theoretical construct. Every single thermodynamic system exists in a particular state. When a system is taken through a series of different states and finally returned to its initial state, a thermodynamic cycle is said to have occurred. In the process of going through this cycle, the system may perform work on its surroundings, thereby acting as a heat engine. A system undergoing a Carnot cycle is called a Carnot heat engine, although such a "perfect" engine is only a theoretical construct and cannot be built in practice. ==Stages== The Carnot cycle when acting as a heat engine consists of the following steps: #Reversible isothermal expansion of the gas at the "hot" temperature, ''T''''1'' (isothermal heat addition or absorption). During this step (1 to 2 on Figure 1, A to B in Figure 2) the gas is allowed to expand and it does work on the surroundings. The temperature of the gas does not change during the process, and thus the expansion is isothermal. The gas expansion is propelled by absorption of heat energy Q1 and of entropy from the high temperature reservoir. #Isentropic (reversible adiabatic) expansion of the gas (isentropic work output). For this step (2 to 3 on Figure 1, B to C in Figure 2) the mechanisms of the engine are assumed to be thermally insulated, thus they neither gain nor lose heat. The gas continues to expand, doing work on the surroundings, and losing an equivalent amount of internal energy. The gas expansion causes it to cool to the "cold" temperature, ''T''''2''. The entropy remains unchanged. #Reversible isothermal compression of the gas at the "cold" temperature, ''T''''2''. (isothermal heat rejection) (3 to 4 on Figure 1, C to D on Figure 2) Now the surroundings do work on the gas, causing an amount of heat energy Q2 and of entropy to flow out of the gas to the low temperature reservoir. (This is the same amount of entropy absorbed in step 1, as can be seen from the Clausius inequality.) #Isentropic compression of the gas (isentropic work input). (4 to 1 on Figure 1, D to A on Figure 2) Once again the mechanisms of the engine are assumed to be thermally insulated. During this step, the surroundings do work on the gas, increasing its internal energy and compressing it, causing the temperature to rise to ''T''''1''. The entropy remains unchanged. At this point the gas is in the same state as at the start of step 1. 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Carnot cycle」の詳細全文を読む スポンサード リンク
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